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Rachel Evans
Associate Prof. in Device Fabrication, Chemistry

Publications and Further Research Outputs

Peer-Reviewed Publications

Willis-Fox, N., Kraft, M., Arlt, J., Scherf, U., Evans, R.C., Tunable White-Light Emission from Conjugated Polymer-Di-Ureasil Materials, Advanced Functional Materials, 26, (4), 2016, p532-542 Journal Article, 2016 DOI

Houston J.E, Kraft M, Scherf U, Evans R.C, Sequential detection of multiple phase transitions in model biological membranes using a red-emitting conjugated polyelectrolyte, Physical Chemistry Chemical Physics, 18, (18), 2016, p12423 - 12427 Journal Article, 2016 DOI URL

Houston J.E, Kraft M, Mooney I, Terry A.E, Scherf U, Evans R.C, Charge-Mediated Localization of Conjugated Polythiophenes in Zwitterionic Model Cell Membranes, Langmuir, 32, (32), 2016, p8141 - 8153 Journal Article, 2016 URL DOI

Kaniyoor, A., Mckenna, B., Comby, S., Evans, R.C., Design and Response of High-Efficiency, Planar, Doped Luminescent Solar Concentrators Using Organic-Inorganic Di-Ureasil Waveguides, Advanced Optical Materials, 2016, p444-456 Journal Article, 2016 DOI

M. Chevrier, J. Kesters, C. Blayo, S. Richeter, A. Van Der Lee, O. Coulembier, M. Surin, A. Mehdi, R. Lazzaroni, R.C. Evans, W. Maes, P. Dubois and S. Clément, Regioregular Polythiophene-Porphyrin Supramolecular Copolymers for Optoelectronic Applications, Macromolecular Chemistry and Physics, 2016 Journal Article, 2016 TARA - Full Text DOI

Chevrier M, Richeter S, Coulembier O, Surin M, Mehdi A, Lazzaroni R, Evans RC, Dubois P, Clément S, Expanding the light absorption of poly(3-hexylthiophene) by end-functionalization with "-extended porphyrins., Chemical communications (Cambridge, England), 52, 2016, p171 - 174 Journal Article, 2016 TARA - Full Text DOI

Meazzini I, Willis-Fox N, Blayo C, Arlt J, Clément S, Evans R.C, Targeted design leads to tunable photoluminescence from perylene dicarboxdiimide-poly(oxyalkylene)/siloxane hybrids for luminescent solar concentrators, Journal of Materials Chemistry C, 4, (18), 2016, p4049 - 4059 Journal Article, 2016 URL DOI

Willis-Fox N, Belger C, Fennell J.F, Evans R.C, Swager T.M, Threading the Needle: Fluorescent Poly-pseudo-rotaxanes for Size-Exclusion Sensing, Chemistry of Materials, 28, (8), 2016, p2685 - 2691 Journal Article, 2016 URL DOI

Willis-Fox N., Marques A., Marques A., Arlt J., Scherf U., Carlos L., Burrows H., Evans R., Synergistic photoluminescence enhancement in conjugated polymer-di-ureasil organic-inorganic composites, Chemical Science, 6, (12), 2015, p7227-7237 Journal Article, 2015 DOI TARA - Full Text

Chevrier, M., Houston, J.E., Kesters, J., Van Den Brande, N., Terry, A.E., Richeter, S., Mehdi, A., Coulembier, O., Dubois, P., Lazzaroni, R., Van Mele, B., Maes, W., Evans, R.C., Clément, S., Self-assembled conjugated polyelectrolyte-surfactant complexes as efficient cathode interlayer materials for bulk heterojunction organic solar cells, Journal of Materials Chemistry A, 3, (47), 2015, p23905-23916 Journal Article, 2015

A. Thomas, J. E. Houston, N. Van den Brande, J. De Winter, M. Chevrier, R. K. Heenan, A. Terry, S. Richeter, A. Mehdi, B. Van Mele, P. Dubois, R. Lazzaroni, P. Gerbaux, R. C. Evans* and S. Clément*, All-Conjugated Cationic Copolythiophene "Rod-Rod" Block Copolyelectrolytes: Synthesis, Optical Properties and Solvent-Dependent Assembly, Polymer Chemistry, 5, 2014, p3352 - 3362 Journal Article, 2014 TARA - Full Text

A. R. Patterson, W. Schmitt*, R. C. Evans*, Lighting-Up Two-Dimensional Lanthanide Phosphonates: Tunable Structure-Property Relationships towards Visible and Near-Infrared Emitters., Journal of Physical Chemistry C, 118, 2014, p10291 - 10301 Journal Article, 2014 URL

Houston JE, Patterson AR, Jayasundera AC, Schmitt W, Evans RC, Charge-modulated self-assembly and growth of conjugated polyelectrolyte-polyoxometalate hybrid networks., Chemical Communications, 50, 2014, p5233 - 5235 Journal Article, 2014 TARA - Full Text DOI

Patricia C. Marr, Katherine McBride, Rachel C. Evans*, Sugar-derived organogels as templates for structured, photoluminescent conjugated polymer-inorganic hybrid materials, Chemical Communications, 49, 2013, p6155 - 6157 Journal Article, 2013

E. Hashem, A.N. Swinburne, C. Schulzke, R.C. Evans, J.A. Platts, A. Kerridge, L.S. Natrajan and R.J. Baker, Emission Spectroscopy of Uranium(IV) Compounds: A Combined Synthetic, Spectroscopic and Computational Study, RSC Advances, 3, 2013, p4350 - 4361 Journal Article, 2013 DOI TARA - Full Text

Rachel C. Evans, Harnessing Self-Assembly Strategies for The Rational Design of Conjugated Polymer Based Materials. , Journal of Materials Chemistry C, 1, 2013, p4190 - 4200 Journal Article, 2013 TARA - Full Text DOI

Rachel C. Evans*, Matti Knaapila, Niamh Willis-Fox, Mario Kraft, Ann Terry, Hugh D. Burrows, Ullrich Scherf, Cationic Polythiophene-Surfactant Self-Assembly Complexes: Phase Transitions, Optical Response, and Sensing, Langmuir, 28, 2012, p12348 - 12356 Journal Article, 2012

Rachel C. Evans*, Patricia C. Marr, Chain confinement promotes beta-phase formation in polyfluorene-based luminescent ionogels, Chemical Communications, 48 , (31), 2012, p3742 - 3744 Journal Article, 2012

Matti Knaapila, Rachel C. Evans, Andrea Gutacker, Vasil M. Garamus, Noémi K. Székely, Ullrich Scherf and Hugh D. Burrows , Conjugated polyelectrolyte (CPE) poly[3-[6-(N-methylimidazolium)hexyl]-2,5-thiophene] complexed with aqueous sodium dodecylsulfate amphiphile: synthesis, solution structure and "surfactochromic" properties, Soft Matter, 7, 2011, p6863 - 6872 Journal Article, 2011

Pereira, RFP, Tapia, MJ, Valente, AJM, Evans, RC, Burrows, HD, Carvalho, RA, On the flocculation and re-dissolution of trivalent lanthanide metal ions by sodium dodecyl sulfate in aqueous solutions, Journal of Colloid and Interface Science, 354, 2011, p166 - 174 Journal Article, 2011

Yonet-Tanyeri N, Evans R.C, Tu H, Braun P.V, Molecular transport directed via patterned functionalized surfaces, Advanced Materials, 23, (15), 2011, p1739 - 1743 Journal Article, 2011 DOI URL

Gutacker, A, Koenen, N, Scherf, U, Adamczyk, S, Pina, J, Fonseca, SM, Valente, AJM, Evans, RC, de Melo, JS, Burrows, HD, Knaapila, M, Cationic fluorene-thiophene diblock copolymers: Aggregation behaviour in methanol/water and its relation to thin film structures, POLYMER, 51, 2010, p1898 - 1903 Journal Article, 2010

Knaapila, M, Vaughan, HL, Hase, TPA, Evans, RC, Stepanyan, R, Torkkeli, M, Burrows, HD, Scherf, U, Monkman, AP, Concentration Effect on the Oriented Microstructure in Tensile Drawn Polyfluorene-Polyethylene Blend, MACROMOLECULES, 43, 2010, p299 - 305 Journal Article, 2010

Knaapila, M, Evans, RC, Almásy, L, Garamus, VM, Székély, NK, Gutacker, A, Scherf, U, Burrows, HD, Structure and "Surfactochromic" Properties of Conjugated Polyelectrolyte (CPE)- Surfactant Complexes between a Cationic Polythiophene and SDS in Water, Langmuir, 26, 2010, p15634 - 15643 Journal Article, 2010 DOI

Gutacker, A, Adamczyk, S, Helfer, A, Garner, LE, Evans, RC, Fonseca, SM, Knaapila, M, Bazan, GC, Burrows, HD, Scherf, U, All-conjugated polyelectrolyte block copolymers, JOURNAL OF MATERIALS CHEMISTRY, 20, 2010, p1423 - 1430 Journal Article, 2010

Knaapila, M, Evans, RC, Gutacker, A, Garamus, VM, Torkkeli, M, Adamczyk, S, Forster, M, Scherf, U, Burrows, HD, Solvent Dependent Assembly of a Polyfluorene-Polythiophene "Rod-Rod" Block Copolyelectrolyte: Influence on Photophysical Properties, LANGMUIR, 26, 2010, p5056 - 5066 Journal Article, 2010

Evans, RC, Macedo, AG, Pradhan, S, Scherf, U, Carlos, LD, Burrows, HD, Fluorene Based Conjugated Polyelectrolyte/Silica Nanocomposites: Charge-Mediated Phase Aggregation at the Organic-Inorganic Interface, ADVANCED MATERIALS, 22, 2010, p3032 - 3037 Journal Article, 2010

Evans, RC, Douglas, P, Design and Color Response of Colorimetric Multilumophore Oxygen Sensors, ACS APPLIED MATERIALS & INTERFACES, 1, 2009, p1023 - 1030 Journal Article, 2009

Evans, RC, Douglas, P, Winscom, CJ, Photophysics and Electrochemistry of some Thione Far-Red/Near-IR Triplet Emitters, JOURNAL OF FLUORESCENCE, 19, 2009, p169 - 177 Journal Article, 2009

Preface in, editor(s)Raquel de Pedro Ricoy, Isabelle Perez and Christine Wilson , Interpreting and Translating in Public Service Settings Policy, Practice, Pedagogy, Manchester, St. Jerome, 2009, ppvii - viii, [Lorraine Leeson ] Book Chapter, 2009

Evans, RC, Ananias, D, Douglas, A, Douglas, P, Carlos, LD, Rocha, J, Energy transfer and emission decay kinetics in mixed microporous lanthanide silicates with unusual dimensionality, JOURNAL OF PHYSICAL CHEMISTRY C, 112, 2008, p260 - 268 Journal Article, 2008

Evans, RC, Carlos, LD, Douglas, P, Rocha, J, Tuning the emission colour in mixed lanthanide microporous silicates: energy transfer, composition and chromaticity, JOURNAL OF MATERIALS CHEMISTRY, 18, 2008, p1100 - 1107 Journal Article, 2008

Evans RC, Douglas P, Winscom CJ, Coordination complexes exhibiting room-temperature phosphorescence: evaluation of their suitability as triplet emitters for light-emitting diodes, Coordination Chemistry Reviews, 250, 2006, p2093 - 2126 Review Article, 2006

Evans, RC, Douglas, P, Williams, JAG, Rochester, DL, A novel luminescence-based colorimetric oxygen sensor with a "traffic light" response, Journal of Fluorescence, 16, 2006, p201 - 206 Journal Article, 2006

Evans, RC, Douglas, P, Controlling the color space response of colorimetric luminescent oxygen sensors, ANALYTICAL CHEMISTRY, 78, 2006, p5645 - 5652 Journal Article, 2006

Doerr, SH, Douglas, P, Evans, RC, Morley, CP, Mullinger, NJ, Bryant, R, Shakesby, RA, Effects of heating and post-heating equilibration times on soil water repellency, AUSTRALIAN JOURNAL OF SOIL RESEARCH, 43, 2005, p261 - 267 Journal Article, 2005

Non-Peer-Reviewed Publications

Editors: Rachel C. Evans, Peter Douglas, Hugh D. Burrows, Applied Photochemistry, Springer, 2013 Book, 2013

The Photochemical Laboratory in, editor(s)R. C. Evans, P. Douglas, H. D. Burrows , Applied Photochemistry, Springer, 2013, [Peter Douglas, Rachel C. Evans, Hugh D. Burrows] Book Chapter, 2013

Photochemical Materials: Absorbers, Emitters, Displays Sensitisers, Acceptors, Traps and Photochromics in, editor(s)R. C. Evans, P. Douglas, H. D. Burrows , Applied Photochemistry, Springer, 2013, [Matthew L. Davies, Peter Douglas, Rachel C. Evans, Hugh D. Burrows] Book Chapter, 2013

Optical Sensors and Probes in, editor(s)R. C. Evans, P. Douglas, H. D. Burrows , Applied Photochemistry, Springer, 2013, [Rachel C. Evans, Peter Douglas] Book Chapter, 2013

Foundations of Photochemistry in, editor(s)R. C. Evans, P. Douglas, H. D. Burrows , Applied Photochemistry, Springer, 2013, [Peter Douglas, Hugh D. Burrows, Rachel C. Evans] Book Chapter, 2013

All-Conjugated Rod-Rod Diblock Copolymers containing Conjugated Polyelectrolyte (CPE) Blocks in, editor(s)B. Liu, G.C. Bazan , Conjugated Polyelectrolyes. Fundamentals and Applications , Weinheim, Wiley-VCH, 2012, [U. Scherf, R. C. Evans, A. Gutacker, G. C. Bazan] Book Chapter, 2012

Preface in, first reprint of R.A.S. Macalister's Corpus Inscriptionum Insularum Celticarum, Four Courts Press, 1996, [McManus D.] Book Chapter, 1996

Research Expertise

Description

Current research broadly covers the design and characterisation of luminescent inorganic-organic hybrid materials for application in sensors, photovoltaics and optoelectronic devices. Inorganic-organic nanocomposites exhibit physicochemical characteristics that lie at the interface of the organic and inorganic realms, offering significant potential for the preparation of multifunctional "smart" materials. Self-assembly of organic lumophores such as conjugated polyelectrolytes can lead to a complex supramolecular assemblies, which may be use to tune optical and charge-transport properties. The challenge undertaken here is to direct the self-organisation of the emissive organic component within an inorganic matrix/surface to obtain simultaneous control of morphology and electronic properties, which is often a prerequisite for many of the above applications. By understanding self-assembly-property relationships on the molecular level, we aim to design high performance tailor-made nanostructured devices. Current focus: 1. External control of self-organisation in conjugated polymer-inorganic-organic hybrids: from solution to microstructure thin films, coated nanotubes and nanoparticles. 2. Colorimetrc luminescent sensors: polymer arrays and nanostructured thin films for the detection of explosives and volatile organic compounds. 3. Structural hierarchy-electronic property relationships: exciton migration, energy transfer, modelling and colour tuning in systems of reduced dimensionality.

Projects

  • Title
    • High-Efficiency Conjugated Polymer-Inorganic Hybrids as Luminescent Solar Concentrators for Photovoltaics
  • Funding Agency
    • Science Foundation Ireland
  • Date From
    • 01/02/2013
  • Date To
    • 31/01/2017
  • Title
    • CHROMOXYSENSE: Intelligent Colorimetric Luminescent Oxygen Sensor Formulations as Integrity Indicators for Modified Atmosphere Packaged Foods
  • Funding Agency
    • Enterprise Ireland
  • Date From
    • 01/02/2014
  • Date To
    • 31/11/2015
  • Title
    • Hybrid Organic-Inorganic Polymers: Novel Waveguides and Device Architectures for Luminescent Solar Concentrators with Superior Collecting Efficiencies
  • Funding Agency
    • Science Foundation Ireland
  • Date From
    • 01/03/2015
  • Date To
    • 30/06/2016
  • Title
    • Controlled Assembly of Conjugated Polymer Building Blocks into Nanostructured Hybrid Thin Film Devices
  • Funding Agency
    • Irish Research Council
  • Date From
    • 01/09/2011
  • Date To
    • 30/08/2015
  • Title
    • Solvent- and Charge-Mediated Self-Assembly of Conjugated Polyelectrolyte Block Copolymers for Sensing and Photovoltaic Device Applications
  • Funding Agency
    • Irish Research Council
  • Date From
    • 2014
  • Title
    • Structure-Property Correlation in Luminescent Multi-Component Hybrid Nanostructures
  • Funding Agency
    • RSC Research Fund
  • Date From
    • January 2010
  • Date To
    • December 2010
  • Title
    • Structure-Property Correlation in Conjugated Polythiophenes
  • Funding Agency
    • Royal Irish Academy
  • Date From
    • November 2009
  • Date To
    • October 2010
  • Title
    • FRET-based Conjugated Polymer Macromolecular Switch for Bio-Anion Recognition
  • Funding Agency
    • Laser Lab Europe
  • Date From
    • 2010
  • Title
    • Microstructural Organisation in Luminescent Conjugated Polymer-Silicate Organic-Inorganic Nanocomposites
  • Funding Agency
    • MAX-lab/EU-ELISA
  • Date From
    • 2009

Keywords

Composite materials; Condensed matter, optical and dielectric properties; Condensed matter, soft matter and polymer physics; Lanthanides; Macromolecular chemistry; Materials, Physical Properties; Multisensory technology, multi sensing; Nanochemistry; Nanotechnology; Neutron Scattering; Optical materials; Organic Coatings; Photochemistry and photophysics; Photovoltaic Materials; Photovoltaic systems, cells and modules manufacturing; Physical Chemistry; Polymer technology, biopolymers; Polymers; Sensory science, sensors and instrumentation; Solar, Photochemical Conversion; Spectroscopy


Last updated 24 August 2016 by School of Chemistry (Email).