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Biography

Dr Bob Baker was born in 1975 in Blaenavon, South Wales. He completed his undergraduate degree at the University of Warwick and carried out his PhD studies under the supervision of Prof. P. G. Edwards at Cardiff University (1997-2001) on early transition metal triphosphamacrocycles. He then worked as a postdoctoral research fellow with Prof. Cameron Jones (2001-2005), working on low oxidation state group 13 compounds. He was then awarded an Alexander von Humboldt Research Fellowship held at the Technische Universität Braunschweig, working with Prof. Dr. Matthias Tamm on substituted cyclohepatrienyl early transition metal complexes. From 2006-2008 he was a Lecturer in Inorganic Chemistry at Nottingham Trent University, before moving to Trinity College in January 2009. His research interests are in fundamental and applied actinide chemistry and the development of new transition metal complexes for catalysis

Publications and Further Research Outputs

Peer-Reviewed Publications

S. Nuzzo, M. P. Browne, B. Twamley, M. E. G. Lyons and R. J. Baker, A structural and spectroscopic study of the first uranyl selenocyanate, [Et4N]3[UO2(NCSe)5], Inorganics, 4, 2016, p4 - 8 Journal Article, 2016 URL DOI TARA - Full Text

Nuzzo S, Twamley B, Platts J.A, Baker R.J, Characterisation of isothiocyanic acid, HNCS, in the solid state: Trapped by hydrogen bonding, Chemical Communications, 52, (90), 2016, p13296 - 13298 Journal Article, 2016 DOI URL

Ikram M, Rehman S, Khan A, Baker R.J, Hofer T.S, Subhan F, Qayum M, Faridoo, Schulzke C, Erratum: Corrigendum to †Synthesis, characterization, antioxidant and selective xanthine oxidase inhibitory studies of transition metal complexes of novel amino acid bearing Schiff base ligand†(Inorganica Chimica Acta (2015) 428 (117â€"126) (S0020169315000249) (10.1016/j.ica.2015.01.021)), Inorganica Chimica Acta, 453, 2016, p779- Journal Article, 2016 DOI URL

Cullen R.J, Jayasundara D.R, Baker R.J, O'Connell G, Donnelly T, Ballantine K.E, Lunney J.G, Colavita P.E, Laser-driven rapid functionalization of carbon surfaces and its application to the fabrication of fluorinated adsorbers, RSC Advances, 6, (86), 2016, p82924 - 82932 Journal Article, 2016 URL DOI

S. Biswas, R. Steudner, M. Schmidt, C. McKenna, L. L. Vintro, B. Twamley and R.J. Baker, An investigation of the interactions of Eu3+ and Am3+ with uranyl minerals: implications for the storage of spent nuclear fuel., Dalton Transactions, 45, 2016, p6383 - 6393 Journal Article, 2016 URL TARA - Full Text DOI

Dipti Patel, Ashley J. Wooles, Emtithal Hashem, Harrison Omorodion, Robert J. Baker and Stephen T. Liddle, Comments on reactions of oxide derivatives of uranium with hexachloropropene to give UCl4, New Journal of Chemistry, 2015, p7559-7562 Journal Article, 2015 TARA - Full Text DOI

Omorodion, Harrison; Twamley, Brendan; Platts, James; Baker, Robert, Further Evidence on the Importance of Fluorous-Fluorous Interactions in Supramolecular Chemistry: A Combined Structural and Computational Study, Crystal Growth and Design, 15, 2015, p2835 - 2841 Journal Article, 2015 URL DOI

M. Ikram, S. Rehman, A. Khan, R. J. Baker, T.S. Hofer, F. Subhan, M. Qayum, Faridoon, C. Schulzke, Synthesis, characterization, antioxidant and selective xanthine oxidase inhibitory studies of transition metal complexes of novel amino acid bearing Schiff base ligand, Inorganica Chimica Acta, 428, 2015, p117 - 126 Journal Article, 2015 URL DOI

Emtithal Hashem, Thomas McCabe, Carola Schulzke and Robert J. Baker, Synthesis, Structure and Photophysical Properties of [UO2X2(O=PPh3)2] (X = Cl, Br, I), Dalton Transactions, 43, 2014, p1125 - 1131 Journal Article, 2014 TARA - Full Text DOI URL

Aurora Walshe, Tim Prüßmann, Tonya Vitova and Robert J. Baker, An EXAFS and HR-XANES Study of the Uranyl Peroxides [UO2(η2-O2)(H2O)2].nH2O (n = 0,2) and Uranyl (Oxy)hydroxide [(UO2)4O(OH)6].6H2O, Dalton Transactions, 43, (11), 2014, p4400-7 Journal Article, 2014 DOI TARA - Full Text

Robert J Baker, Uranium Minerals and their Relevance to Long Term Storage of Nuclear Fuels, Coordination Chemistry Reviews, 266-267, 2014, p123-136 Journal Article, 2014 URL DOI

Emtithal Hashem, James A. Platts, Frantisek Hartl, Giulia Lorusso, Marco Evangelisti, Carola Schulzke, Robert J. Baker, , Thiocyanate complexes of uranium in multiple oxidation states: a combined structural, magnetic, spectroscopic, spectroelectrochemical and theoretical study, Inorganic Chemistry, 53, 2014, p8624 - 8637 Journal Article, 2014

Walshe A, Fang J, Maron L, Baker RJ, New mechanism for the ring-opening polymerization of lactones? Uranyl aryloxide-induced intermolecular catalysis., Inorganic chemistry, 52, (15), 2013, p9077-86 Journal Article, 2013 DOI

E. Hashem, A.N. Swinburne, C. Schulzke, R.C. Evans, J.A. Platts, A. Kerridge, L.S. Natrajan and R.J. Baker, Emission Spectroscopy of Uranium(IV) Compounds: A Combined Synthetic, Spectroscopic and Computational Study, RSC Advances, 3, 2013, p4350 - 4361 Journal Article, 2013 DOI TARA - Full Text

Emtithal Hashem, Giulia Lorusso, Marco Evangelisti, Thomas McCabe, Carola Schulzke, James A. Platts and Robert J. Baker, Fingerprinting the oxidation state of U(IV) by emission spectroscopy, Dalton Transactions, 42, 2013, p14677 - 14680 Journal Article, 2013 DOI TARA - Full Text URL

Muhammad Ikram, Sadia Rehman, Faridoon, Robert J. Baker, Hanif Ur Rehman, Ajmal Khan, Muhammad Iqbal Choudhary, Saeed-Ur -Rehman, Synthesis and distinct urease enzyme inhibitory activities of metal complexes of Schiff-base ligands: Kinetic and thermodynamic parameters evaluation from TG-DTA analysis, Thermochimica Acta, 555, 2013, p72 - 80 Journal Article, 2013 DOI URL

Muhammad Ikram, Sadia Rehman, Muhammad Ali, Faridoon, Carola Schulzke, Robert J. Baker, Alexander James Blake, Khan Malook, Henry Wong, Saeed-Ur-Rehman, Urease and α-chymotrypsin inhibitory activities of transition metal complexes of new Schiff base ligand: Kinetic and thermodynamic studies of the synthesized complexes using TG DTA pyrolysis, Thermochimica Acta, 562, 2013, p22 - 28 Journal Article, 2013 URL DOI

S. Rehman, M. Ikram, R. J Baker, M. Zubair, E. Azad, S. Min, K. Riaz, KH Mok and S.-U. Rehman, Synthesis, characterization, in vitro antimicrobial, and U2OS tumoricidal activities of different coumarin derivatives, Chemistry Central Journal, 7, 2013, p1-12 Journal Article, 2013 URL TARA - Full Text DOI

Rehman, S, Ikram, M, Khan, A, Min, S, Azad, E, Hofer, TS, Mok, KH, Baker, RJ, Blake, AJ, Rehman, SU, New dicoumarol sodium compound: crystal structure, theoretical study and tumoricidal activity against osteoblast cancer cells, Chemistry Central Journal, 7, 2013, p110- Journal Article, 2013 TARA - Full Text DOI

M. Ikram, S.-Ur-Rehman, S. Rehman, R. J. Baker and C. Schulzke, Synthesis, characterization and distinct butyrylcholinesterase activities of transition metal complexes of 2-[(E)-(quinolin-3-ylimino)methyl]phenol, Inorganica Chimica Acta, 390, 2012, p210 - 216 Journal Article, 2012 DOI URL

C. Mallon, A. Walshe, R. J. Forster, T. E. Keyes, and R. J. Baker, The Physical Characterization and Reactivity of the Uranyl Peroxide [UO2(2-O2)(H2O)2].2H2O: Implications for Storage of Spent Nuclear Fuels, Inorganic Chemistry, 51, 2012, p8509 - 8515 Journal Article, 2012 URL DOI

R.J. Baker and A Walshe, Ring Opening Polymerisation of Epoxides Catalysed by a Uranyl Aryloxide and Uranyl Chloride. , Chemical Communications, 48, 2012, p985 - 987 Journal Article, 2012 TARA - Full Text URL DOI

R. J. Baker, P.E. Colavita, D. Murphy, J. A. Platts and J. D. Wallace, Fluorine-Fluorine Interactions in the Solid State: An Experimental and Theoretical Study, Journal of Physical Chemistry A, 116, 2012, p1435 - 1444 Journal Article, 2012 DOI

R. J. Baker, New reactivity of the uranyl ion, Chemistry - A European Journal, 18, 2012, p16258 - 16271 Journal Article, 2012 DOI

R.J. Baker, The Coordination and Organometallic Chemistry of UI3 and U{N(SiMe3)2}3: Synthetic Reagents par excellence, Coordination Chemistry Reviews, 256, 2012, p2843 - 2871 Journal Article, 2012 URL DOI

M. Ikram and R.J. Baker, Fluorous Catalyst Recycling Utilising Highly Fluorinated Zinc Compounds: Ring Opening Polymerisation of e-Caprolactone, Journal of Fluorine Chemistry, 139, 2012, p58 - 62 Journal Article, 2012 TARA - Full Text

Jian Fang, Aurora Walshe, Laurent Maron and Robert J Baker, Ring Opening Polymerization of Epoxides Catalyzed by Uranyl Complexes: An Experimental and Theoretical Study of the Reaction Mechanism, Inorganic Chemistry, 51, 2012, p9132 - 9140 Journal Article, 2012 URL DOI

Julia Baker, Robert J Baker and Carola Schulzke, Perfluorinated Oxygen and Sulfur Containing Compounds as Extractants for Gold(III), Gold Bulletin, 44, (2), 2011, p79 - 83 Journal Article, 2011 URL DOI

R.J. Baker, J. Fuchs, A.J. Richards and H.V. Ogilvie, Perfluorinated Phosphine Oxide and Sulfide Ligands as Extractants for Heavy Metals and Radionuclides, Journal of Environmental Management, 92, 2011, p2781 - 2785 Journal Article, 2011 DOI URL

R.J. Baker, H.V. Ogilvie and A.J. Richards, Perfluorinated Phenols as Extraction Agents for Cs+ and Sr2+. , Radiochimica Acta, 98, 2010, p507 - 511 Journal Article, 2010 DOI

R.J. Baker and E. Hashem, A Study of the Reactivity of Secondary Phosphines with Radical Sources: A New Dehydrocoupling Reaction. , Helvetica Chimica Acta, 93, 2010, p1081 - 1085 Journal Article, 2010 DOI URL

R.J. Baker, E. Hashem, M. Motevalli, H.V. Ogilvie and A. Walshe, 38. The Coupling of Pyridine and Dichloromethane Mediated by UO2Cl2, Zeitschrift fuer Anorganish und Algamaigne Chemie, 636, 2010, p443 - 445 Journal Article, 2010 URL

R.J. Baker, T. McCabe, J.E. O'Brien, and H.V. Ogilvie, 39. Thermomorphic Metal Scavengers: A synthetic and multinuclear NMR study of highly fluorinated ketones and their application in heavy metal removal. , Journal of Fluorine Chemistry, 131, 2010, p621 - 626 Journal Article, 2010 DOI URL

R.J. Baker and H. V. Ogilvie, Nottingham Trent University, A New Process for Soil Remediation using a Supercritical Solvent, 2009, WO2009109754A1. Patent, 2009

R. J. Baker, C. Jones, D. P. Mills, G. A. Pierce and M. Waugh, Investigations into the preparation of groups 13-15 N-heterocyclic carbene analogues. , Inorg. Chim. Acta, 361, 2008, p427 - 435 Journal Article, 2008 DOI

Molybdenum compounds containing CO and/or isocyanides in, editor(s)R.H. Crabtree and D.M.P. Mingos , Comprehensive Organometallic Chemistry III, Elsevier, 2007, pp391 - 512, [Robert J Baker and Matthias Tamm] Book Chapter, 2007

S. Aldridge, R.J. Baker, N.D. Coombs, C. Jones, R.P. Rose, A. Rossin and D.J. Willock, , Complexes of a gallium heterocycle with transition metal dicyclopentadienyl and cyclopentadienylcarbonyl fragments, and with a dialkylmanganese compound. , Dalton Trans., , 2006, p3313 - 3320 Journal Article, 2006 TARA - Full Text DOI

R.J. Baker, C. Jones, D.P. Mills, D.M. Murphy E. Hey-Hawkins and R. Wolf,, The reactivity of Gallium-(I), -(II) and -(III) heterocycles towards group 15 substrates: Attempts to prepare gallium-terminal pnictinidene complexes. , Dalton Trans, 2006, p67 - 72 Journal Article, 2006 TARA - Full Text DOI

R.J. Baker and C. Jones, Synthesis and Characterisation of Sterically Bulky Lithium Amidinate and Bis-amidinate Complexes. , J. Organomet. Chem. , 691, 2006, p65 - 71 Journal Article, 2006 DOI

. R.J. Baker, T. Bannenberg, A. Kunst, S. Randoll and M. Tamm,, Adduct formation of [( Ø7-C7H7)Zr( Ø5-C5H5)] with phosphines and N-heterocyclic carbenes: A combined structural, thermodynamic and theoretical study. , Inorg. Chim. Acta, , 359, 2006, p4797 - 4801 Journal Article, 2006 DOI

R.J. Baker, R.D. Farley, C. Jones, D.P. Mills, M. Kloth and D.M. Murphy, , An EPR and ENDOR investigation of a series of diazabutadiene-group 13 complexes., Chem. Eur. J., , 11, 2005, p2972 - 2982 Journal Article, 2005 DOI

R.J. Baker, C. Jones and M. Kloth, Oxidation reactions of an anionic gallium(I) N-heterocyclic carbene analogue with group 16 compounds., Dalton Trans, 2005, p2106 - 2110 Journal Article, 2005 TARA - Full Text DOI

K.L. Antcliff, R.J. Baker, C. Jones, D.M. Murphy and R.P. Rose, Reactions of a gallium(II)-diazabutadiene dimer, [[(H)C(But)N]2}GaI}2], with [ME(SiMe3)2] (M = Li or Na; E = N, P or As): Structural, EPR and ENDOR characterization of paramagnetic gallium(III) pnictide complexes., Inorg. Chem, 44, 2005, p2098 - 2105 Journal Article, 2005 DOI

R.J. Baker and C. Jones, "GaI": A versatile reagent for the synthetic chemist., Dalton Transaction, 2005, p1341 - 1348 Journal Article, 2005 TARA - Full Text DOI

R.J Baker and C. Jones, The coordination chemistry and reactivity of group 13 metal(I) heterocycles, Coordination Chemistry Reviews, 249, 2005, p1857 - 1869 Journal Article, 2005 DOI

R.J. Baker, C. Jones and D.M. Murphy,, Evidence for the first oxidative addition of a transition metal into a digallane(4): Synthesis, structural characterisation and EPR studies of [Cp2ZrIII{Ga[N(Ar)C(H)]2}2][Li(THF)4], Ar = C6H3Pri2-2,6. , Chem. Commun., , 2005, p1339 - 1341 Journal Article, 2005 TARA - Full Text DOI

R.J. Baker, C. Jones, M. Kloth and D.P. Mills, , The reactivity of Gallium(I) and Indium(I) halides towards bipyridines, terpyridines, imino-substituted pyridines and bis(imino)acenaphthenes., New J. Chem, 28, 2004, p207 - 213 Journal Article, 2004 DOI

R.J. Baker, C. Jones, P.C. Junk and M. Kloth, Kinetic control over the thermal stability of the In-H bond: Synthesis and characterisation of amido indium hydride complexes. , Angew. Chem. Int. Ed., 43, 2004, p3852 - 3855 Journal Article, 2004 DOI

R.J. Baker, H. Bettentrup and C. Jones,, The synthesis and structural characterisation of the first gallium(II) dialkylphosphide complex, Inorg. Chem. Commun, 7, 2004, p1289 - 1291 Journal Article, 2004 DOI

R.J. Baker and C. Jones, The molecular structure of ditriptycenyl ditelluride, Main Group Met. Chem. , 27, 2004, p323 - 325 Journal Article, 2004

R.J. Baker, C. Jones, M. Kloth and J. A. Platts,, Oxidative coupling of an anionic gallium(I) carbene analogue: Synthesis and structural characterisation of an unprecedented à-cyclopentadienyl-bridged digallane complex, Organometallics, 23, 2004, p4811 - 4813 Journal Article, 2004 DOI

R.J. Baker, M. Brym, C. Jones and M. Waugh,, 9-Triptycenyl complexes of Group 13 and 15 halides and hydrides. , J. Organomet. Chem., , 689, 2004, p781 - 790 Journal Article, 2004 DOI

C.D. Abernathy, R.J. Baker, M.L. Cole, A.J. Davies and C. Jones,, Reactions of a carbene stabilized indium trihydride complex, [InH3{CN(Mes)C2H2N(Mes)}] Mes = mesityl, with transition metal complexes. , Transition Met. Chem, 28, 2003, p296 - 299 Journal Article, 2003 DOI

R.J. Baker, C. Jones and J.A. Platts, Analogies between the reactivities of an anionic gallium(I) heterocycle and N-heterocyclic carbenes towards metallocenes, J. Am. Chem. Soc., 125, 2003, p10534 - 10535 Journal Article, 2003 DOI

R.J. Baker, C. Jones and J.A. Platts, Synthesis, structural and theoretical studies of an iron-gallium(I) heterocycle complex: Analogies with N-heterocyclic carbene chemistry, Dalton Trans., , 2003, p3673 - 3674 Journal Article, 2003 DOI

R.J. Baker and C. Jones, The reaction of 'GaI' with a 1,3-diyne: Synthesis, characterisation and reactivity of a novel C-C coupled ene-diyne-bis(gem-organodigallium(III)) complex. , Chem. Commun., 2003, p390 - 391 Journal Article, 2003 TARA - Full Text DOI

R.J. Baker, H. Bettentrup and C. Jones, The synthesis of phosphorus heterocycles from tetra-tert-butyltetraphosphacubane, Acta Cryst., C59, 2003, pm339 - m341 Journal Article, 2003 DOI

R.J. Baker and C. Jones, [1,3-Di(mesityl)imidazole-2-ylidene]Gallium Iodide Dihydride, Appl. Organomet. Chem., 17, 2003, p807 - 808 Journal Article, 2003 DOI

R.J. Baker, H. Bettentrup and C. Jones, (2,6-Diisopropylphenyl)isopropyldeneammonium iodide, Acta Cryst., E59, 2003, po538 - o539 Journal Article, 2003 DOI

R.J. Baker, C. Jones, M. Kloth and J.A. Platts, Synthesis and structural characterization of thermally stable group 13 hydride complexes derived from a gallium(I) carbene analogue., Angew. Chem. Int. Edn.,, 42, 2003, p2660 - 2663 Journal Article, 2003 DOI

R.J. Baker and C. Jones, The molecular structure of [{ Ý-Ga(Ar-DAB)2}{ Ý-K(TMEDA)}( Ý-C5H5){ Ý-K(TMEDA)}].(C7H8)1.5, Ar-DAB = {(C6H3Pri2-2,6)NC(H)=}2. , Main Group Met. Chem., , 26, 2003, p267 - 268 Journal Article, 2003

R.J. Baker, H. Bettentrup and C. Jones, The reactivity of primary and secondary amines, secondary phosphanes and N-heterocyclic carbenes towards group 13 metal(I) halides., Eur. J. Inorg. Chem, 2003, p2446 - 2451 Journal Article, 2003 DOI

R.J. Baker, P.G. Edwards, R.D. Farley, D.M. Murphy, J.A. Platts and K.E. Voss, Low valent carbonylvanadium complexes of the triphosphorus macrocycle 12[ane]P3Et3. , J. Chem. Soc., Dalton. Trans., 2003, p944 - 948 Journal Article, 2003 TARA - Full Text DOI

R.J. Baker, R.D. Farley, C. Jones, M. Kloth and D.M. Murphy, Synthesis and characterisation of the first carbene and diazabutadiene-indium(II) complexes., Chem. Commun, 2002, p1196 - 1197 Journal Article, 2002 TARA - Full Text DOI

R.J. Baker, P.G. Edwards J.Gracia-Moria, F. Ingold and K.M.A. Malik, Manganese and Rhenium triphosphorus macrocycle complexes and reactions with alkenes., J. Chem. Soc., Dalton Trans, 2002, p3985 - 3992 Journal Article, 2002 DOI TARA - Full Text

R.J. Baker, R.D. Farley, C. Jones, M. Kloth and D.M. Murphy, The reactivity of diazabutadienes towards low oxidation state group 13 iodides and the synthesis of a new gallium(I) carbene analogue, J. Chem. Soc., Dalton Trans.,, 2002, p3844 - 3850 Journal Article, 2002 DOI TARA - Full Text

R.J. Baker, A.J. Davies, C. Jones and M. Kloth, Structural and spectroscopic studies of carbene and N-donor ligand complexes of group 13 hydrides and halides., J. Organomet. Chem, 656, 2002, p203 - 210 Journal Article, 2002 DOI

R.J. Baker, P.C. Davies, P.G. Edwards, R.D. Farley, S.S. Liyanage, D.M. Murphy and B. Yong, Early transition metal complexes of triphosphorus macrocycles, European Journal of Inorganic Chemistry, 2002, p1975 - 1984 Journal Article, 2002 DOI

R.J. Baker and P.G. Edwards, Transition metal complexes of triphosphorus macrocycles: A new class of homogeneous olefin polymerisation catalysts., Journal of the Chemical Society, Dalton Transactions, 2002, p2960 - 2965 Journal Article, 2002 TARA - Full Text DOI

R.J. Baker, M.L. Cole, C. Jones and M.F. Mahon, , Bidentate N-Heterocyclic carbene complexes of group 13 trihydrides and trihalides., J. Chem. Soc., Dalton Trans, 2002, p1992 - 1996 Journal Article, 2002 DOI TARA - Full Text

G.R. Willey, R.J. Baker, J.V. Haslop, M.P. Spry and M.G.B. Drew, Coordination studies of the ligand series RNH.C.(CH2)n.C.NHR where R = alkyl, aryl;  = O,S and n = 0,1,2. Part 6. Crystal structures and bonding considerations of the ligands MeNH.CO.CH2.CO.NHMe (L1), MeNH.CO.CH2.CH2.CO.NHMe (L4), MeNH.CS.CH2.CS.NHMe (L5) and the SnIV complexes SnBr4L1.L1, SnBr4L2.2THF and SnBr4L3.MeCN where L2 = iC3H7NH.CO.CH2.CO.NHiC3H7 and iC3H7NH.CS.CH2.CS.NHiC3H7. , Polyhedron, (17), 1998, p3291 - 3303 Journal Article, 1998 DOI

Non-Peer-Reviewed Publications

H. Omorodion and R. J. Baker, Recent Advances in Rare Earth Extraction: Where Do WEEE Stand, Irish Chemical News, (2), 2016, p12 - 36 Journal Article, 2016 TARA - Full Text URL

Research Expertise

Description

My research focuses on the organometallic chemistry of p-, d- and f-block metals. Currently work in my group is centred on four different themes. 1. Low Oxidation State Actinide Chemistry. We are examining the coordination and organometallic chemistry of U(III), U(IV) and Th(IV)using a multi-technique approach in order to fully understand the electronic structure. Routinely we use X-ray diffraction, multinuclear NMR, UV-vis/NIR, infrared and raman spectroscopies, temperature dependent cyclic voltammetry and SQUID, as well as computational chemistry. Using these methodologies we are targeting a compehensive uderstanding of simple U(IV) compounds. The synthesis of compounds featuring An-An or An-TM (An = Th or U) multiple bonds is being undertaken in order to probe the effects of the f-orbitals in forming bonds. 2. High Oxidation State Uranium Chemistry. We are examining the catalytic activity of the uranyl ion towards hard monomers to probe new reactivity patterns for the uranyl ion. Additionally we are looking at reduction to the U(V)uranly ions. 3. New heterobimetallic transition metal complexes are being prepared with the aim of preparing new homogeneous catalysts for a variety of processes such as Fischer-Tropsch production of alkanes, and methane activation. 4. A new process is being developed in order to remove toxic metals (e.g. Cr, Cd, Hg, U, Pu) from contaminated soil, and precious metals from e-waste. From the crystal structures of fluorinated extractants we have characterised C-F...F-C interactions in the solid state and by computational chemistry.

Projects

  • Title
    • Unusual Oxidation State Uranium Chemistry
  • Summary
    • We are exploring the chemistry of high oxidation state uranium chemistry. The elucidation of new reactivity pathyways that shed light on the 5f-orbital interaction will be explored. Furthermore, reduction to the Uranyl(V) ion will be explored.
  • Funding Agency
    • IRCSET
  • Date From
    • sept 2009
  • Date To
    • sept 2012
  • Title
    • TOMEX - TOxic Metal EXtraction
  • Summary
    • The contamination of the environment by toxic metals is a major problem that can require expensive clean-up procedures. This project aims to develop an ex-situ soil re-mediation for a number of toxic metals using supercritical CO2 as a solvent. These can be broadly classed as actinide elements and heavy metal waste from industry and mining applications.
  • Funding Agency
    • The Lachesis Fund
  • Date From
    • August 2008
  • Date To
    • February 2009

Keywords

Catalysis; Catalysis/Kinetics; Homogeneous catalysis; Inorganic Chemistry; Lanthanides; Nuclear chemistry; Nuclear/Radioactive Wastes; Organometallic chemistry; Organometallic Chemistry, Main Group; Polymer Chemistry; Polymer technology, biopolymers; Radioactivity; Waste Management

Recognition

Awards and Honours

Alexander von Humboldt Research Scholarship 2005-2006

Memberships

Member of the RSC 2006

Member of the ACS 2006

Fellow of Institute of Chemistry Ireland 2009

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